Science at a Distance

Physical Structure

Electrons, Levels and Energy


Electrons

an orbital

Electrons are one of the three subatomic particles. They have a negative charge and about 1/2000 the mass of a proton. They are attracted to the positively charged protons in the atomic center, but they are repelled by one another. It is impossible to absolutely define the position (momentum and location) of an electron in space and time. Instead electrons are described as having different probabilities of distribution around the atomic center. These volumes of space (where an electron is found more often) are called atomic orbitals
Atomic Orbitals

a p orbital

Atomic orbitals have different shapes. All s are spherical. Electrons in s orbitals have the same probability of being found in any direction and at a given distance from the atomic center. Electrons in an s orbital may even be found right at the atomic center!

In all other types of orbitals occupying electrons have no probability of being found at the center. All p orbitals are shaped somewhat like a dumbbell, with the thin, pinched region of zero probability lying right over the center. No matter what its shape, an orbital can only hold a maximum of two electrons at any time.

Energy Levels

energy levels

Orbitals are grouped in zones at different distances from the atomic center. Electrons in zones close to the center are lower in energy than electrons in zones at greater distances from the center. According to Bohr, the amount of energy needed to move an electron from one zone to another is a fixed, finite amount. These zones are known as energy levels (or sometimes called electron shells).

At the lowest energy level, the one closest to the atomic center, there is a single 1s orbital that can hold 2 electrons.

At the next energy level, there are four orbitals; a 2s, 2p1, 2p2, and a 2p3. Each of these orbitals can hold 2 electrons, so a total of 8 electrons can be found at this level of energy.

In larger and larger atoms, electrons can be found at higher and higher energy levels (e.g. 3s and 3p).

Moving between Levels

moving between energy levels

As Neils Bohr showed, it is possible for electrons to move between energy levels. Light contains energy. If a photon of light strikes an atom, it is possible for the energy in the light ray to be transferred to one of the low energy electrons moving around the atomic center. The electron with its extra packet of energy becomes excited, and promptly moves out of its lower energy level and takes up a position in a higher energy level.

This situation is unstable, however. Almost immediately the excited electron gives up the extra energy it holds, usually in the form of light, and falls back down to the lower energy level again.

Florescence is a phenomenon of moving electrons. Ultra violet ("black") light has a short wavelength and high energy. When these rays hit certain atoms this energy is absorbed as described above. But the electrons cannot hold this energy for long, and when they fall back to the lower energy levels they give off the yellowish "glow" of longer wavelength, lower energy light that we can see with our eyes.

... now you explore
electrons and orbitals
for yourself.
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© 1997, 1998, 1999 Professor John Blamire